Shadow Bibarel

Shadow Bibarel just isn't worth a second glance. It's the rat of the generation, and offers almost nothing even with the coveted Shadow boost.

Best PvE Offensive Moveset

• Water Gun performs better on offense, and actually has a use in PvE.
• Take Down gets STAB, but can't be Super Effective against anything, making it useless.
• Surf enables Bibarel to fulfill a Water-type role.
• Hyper Fang isn't a terrible move, but lacking a Super Effective multiplier is painful. 
• Hyper Beam has no use. 

Best PvE Defensive Moveset

• Take Down is generally better for defense due to stronger stats, but can't be Super Effective.
• Water Gun has worse stats for defense, but is more likely to be resisted by Grass-type attackers.
• Hyper Fang hits harder on defense, and provides neutral coverage at best.
• Surf isn't far behind in defensive performance, but Grass-type attackers laugh at it. 
• Hyper Beam is too slow for defense. 

Water Gun provides decent damage and energy gain. Take Down is one of the worst fast moves in the game. 

Surf (65 power/40 energy) and Hyper Fang (80 power/50 energy) provide great neutral coverage and good shield pressure. Hyper Beam is way too expensive to be useful.